Brunner, Henri and Nuber, Bernhard and Tracht, Torsten (1998) Optically active transition metal complexes. Part 119: New rhodium(I) complexes containing two different types of optically active ligands. TETRAHEDRON-ASYMMETRY, 9 (21). pp. 3763-3771. ISSN 0957-4166
Full text not available from this repository.Abstract
The synthesis of novel rhodium(I) complexes containing two different chiral ligands is described. These ligands are on the one hand (-)-diop and on the other hand various optically active pyrroleimines, which derive from 1-phenylethylamine or 1-cyclohexylethylamine with an (R)- or (S)-configuration. The resulting (-)dioppyrrolylimine-rhodium(I) complexes are diastereomers and are expected to give different stereoselectivities in enantioselective catalysis (double stereoselection). In addition, the synthesis of novel rhodium(I) complexes containing 1,5-cyclooctadiene and various chiral pyrroleoxazoline ligands is described. An the complexes are used in the enantioselective hydrogenation of ketopantolactone (see following paper). (C) 1998 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC CATALYSIS |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Feb 2023 05:28 |
| Last Modified: | 23 Feb 2023 05:28 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49357 |
Actions (login required)
 |
View Item |
