Sauer, Jürgen and Heldmann, Dieter K. and Range, Klaus-Jürgen and Zabel, Manfred (1998) Stannylated alpha-pyrones: Synthesis, halogenation and destannylation reactions. TETRAHEDRON, 54 (42). pp. 12807-12822. ISSN 0040-4020
Full text not available from this repository.Abstract
Ethynyltributyltin undergoes inverse type [4+2] cycloadditions with various 1,3,4-oxadiazin-6-ones to afford two regioisomeric stannylated alpha-pyrones, which can be separated by flash column chromatography. Exposure of the stannanes to elemental halogens in chloroform or THF as solvent yields the corresponding halogeno pyrones. A general exception of this reaction type is also described. Destannylation with dry hydrogen chloride furnishes 3,6-disubstituted alpha-pyrones. (C) 1998 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 1,3,4-OXADIAZIN-6-ONES 4,5-DIAZA-ALPHA-PYRONES; CYCLOADDITIONS; NORBORNADIENE; cycloadditions; tin and compounds; alkynes; pyrones |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Klaus-Jürgen Range Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Feb 2023 06:25 |
| Last Modified: | 23 Feb 2023 06:25 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49438 |
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