Kunkely, Horst and Vogler, Arnd (1998) Photoluminescence of 8-quinolinato(tetracarbonyl)rhenium(I). INORGANIC CHEMISTRY COMMUNICATIONS, 1 (10). pp. 398-401. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
The electronic spectrum of [Rr(CO)(4)(oxinate)] (oxinate = 8-quinolinato) in CH3CN shows a longest-wavelength absorption at lambda(max) =422 nm which is assigned to an intraligand (IL) transition of the coordinated oxinate. The complex displays a weak green fluorescence and a strong red phosphorescence which originates from the (IL)-I-1 and (IL)-I-3 states, respectively. These emissions appear at r.t. in solution as well as in the solid state. While the fluorescence is not affected by oxygen the phosphorescence is completely quenched in the presence of air. (C) 1998 Elsevier Science S.A. All tights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CARBON-DIOXIDE; LUMINESCENCE PROPERTIES; PHOTOINDUCED REDUCTION; EXCITED-STATE; COMPLEXES; TRICARBONYLBROMO(2,2'-BIPYRIDINE)RHENIUM(I); PHOTOCHEMISTRY; photoluminescence; rhenium complexes; carbonyl complexes; oxinate complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Feb 2023 06:50 |
| Last Modified: | 23 Feb 2023 06:50 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49458 |
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