Kunkely, Horst and Vogler, Arnd (1998) Photochemical reductive elimination of nitrogen from triazidogallium(III). Generation of luminescent gallium(I). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 53 (10). pp. 1180-1182. ISSN 0932-0776, 1865-7117
Full text not available from this repository.Abstract
The irradiation of Ga(N-3)(3) in CH3CN leads to a reductive elimination of nitrogen according to the equation Ga-III(N-3)(3) --> (GaN3)-N-I + 3N(2) (phi = 0.002 at lambda(irr) = 254 nm). Ga+ in CH3CN is characterized by its absorption (lambda(max) = 298 nm) and emission (lambda(max) = 475 nm) spectrum.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BASE ADDUCT; PRECURSORS; COMPLEXES; NITRIDE; GAN; ANTIMONY(III); DERIVATIVES; LEAD(II); TIN(II); BLUE; photochemistry; charge transfer; gallium complexes; azide complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 16 Feb 2023 07:01 |
| Last Modified: | 16 Feb 2023 07:01 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49485 |
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