Brunner, Henri and Prommesberger, Markus (1998) Asymmetric catalysis. Part 127: Enantioselective desymmetrization of 2-n-butyl-4,7-dihydro-1,3-dioxepin with (eta(6)-arene)ruthenium(II) half-sandwich complexes. TETRAHEDRON-ASYMMETRY, 9 (18). pp. 3231-3239. ISSN 0957-4166
Full text not available from this repository. (Request a copy)Abstract
(eta(6)-Arene)ruthenium half-sandwich complexes are highly active and stereoselective catalysts in the enantioselective desymmetrization of 2-n-butyl-4,7-dihydro-1,3-dioxepin to give 2-n-butyl-4,5-dihydro-1,3-dioxepin. Enantioselectivities up to 61% ee were achieved. The temperature and solvent dependence of the catalysis as well as the activation of the catalyst were investigated. (C) 1998 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL COMPLEXES; SCHIFF-BASE COMPLEXES; X-RAY STRUCTURE; DIASTEREOSELECTIVE SYNTHESIS; CRYSTAL-STRUCTURES; RUTHENIUM ATOM; LIGAND; STEREOCHEMISTRY |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 16 Feb 2023 07:17 |
| Last Modified: | 16 Feb 2023 07:17 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49491 |
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