A new and simple 'LEGO' system for the synthesis of 2,6-oligopyridines

Pabst, Gunther R. and Sauer, Jürgen (1998) A new and simple 'LEGO' system for the synthesis of 2,6-oligopyridines. TETRAHEDRON LETTERS, 39 (37). pp. 6687-6690. ISSN 0040-4039

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Abstract

The condensation of alpha-arylglyoxals with carboxamidrazones 1 - 2 is the best method for the synthesis of aryl or hetaryl substituted 1,2,4-triazines 3 - 4. These 1,2,4-triazines can be easily transformed to pyridines by [4+2] cycloaddition with bicyclo[2.2.1]hepta-2.5-diene followed by [4+2] cycloreversions of nitrogen and cyclopentadiene. This reaction sequence offers a new, simple and general access to 2,6-oligopyridines 8 - 11 (C) 1998 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: cycloadditions; oligomers; pyridines; triazines
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 16 Feb 2023 09:10
Last Modified: 16 Feb 2023 09:10
URI: https://pred.uni-regensburg.de/id/eprint/49508

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