Kunkely, Horst and Vogler, Arnd (1998) Photooxidation of dicyanoaurate(I) induced by metal-to-ligand charge transfer excitation. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 53 (8). pp. 853-855. ISSN 0932-0776, 1865-7117
Full text not available from this repository.Abstract
The irradiation of [Au(CN)(2)](-) in oxygen-saturated acetonitrile leads to photooxidation of Au(I). In the presence of additional chloride [Au(CN)(2)Cl-2](-) is formed with phi = 0.5 x 10(-4) at lambda(irr) = 254 nm. It is assumed that [Au(CN)(2)](-) in its metal-to-ligand charge transfer state undergoes an excited state electron transfer to oxygen in the primary photochemical step.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | GOLD(I) PHOSPHINE COMPLEXES; RAY CRYSTAL-STRUCTURE; SPECTROSCOPIC PROPERTIES; PHOTOPHYSICAL PROPERTIES; 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE TPA; SOLID-STATE; LUMINESCENCE; TRINUCLEAR; EMISSION; SPECTRA; photochemistry; charge transfer; gold complexes; cyanide complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Feb 2023 10:12 |
| Last Modified: | 23 Feb 2023 10:12 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49657 |
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