Keßler, Angela and Kensy, Uwe and Dick, Bernhard (1998) NO product yield excitation spectrum of the S-0 -> S-2 transition of nitrosobenzene in a supersonic jet. CHEMICAL PHYSICS LETTERS, 289 (5-6). pp. 516-520. ISSN 0009-2614, 1873-4448
Full text not available from this repository.Abstract
The absorption spectrum of the S-0 --> S-2 transition of ultracold nitrosobenzene in a supersonic jet was measured indirectly by monitoring the product yield of the NO fragment. The vibrational structure and relative line intensities are in good agreement with the corresponding spectrum in an argon matrix. It is concluded that the yield of photofragmentation is constant for all vibronic S-2-states up to an excess energy of 3500 cm(-1). The electronic origin line has a Lorentzian lineshape with a homogeneous width of (90 +/- 5) cm(-1). This corresponds to a lifetime of tau(S-2) = 60 +/- 3 fs. (C) 1998 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | UV ABSORPTION-SPECTRUM; COOLED AZULENE; SOLID ARGON; SPECTROSCOPY; RELAXATION |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Feb 2023 06:38 |
| Last Modified: | 24 Feb 2023 06:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49732 |
Actions (login required)
 |
View Item |
