Kunkely, Horst and Vogler, Arnd (1998) Photochemical hydrogen transfer from bis(i-propylcyclopentadienyl) tungsten dihydride to 9,10-phenanthrenequinone induced by outer sphere charge transfer excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 1 (6). pp. 200-202. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
The electronic spectrum of the addition compound (i-C(3)H(7)C(5)H(4))(2)WH(2). 9,10-phenanthrenequinone displays a longest wavelength absorption at lambda(max) = 530 nm which is assigned to an outer sphere charge transfer (OSCT) transition from the hydride complex to the quinone. OSCT excitation of the complex leads to hydrogen transfer from the hydride to the quinone. This photoreaction which yields 9, 10-phenanthrenediol proceeds with phi= 0.01 at lambda(irr) = 546 nm. (C) 1998 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | photochemistry; charge transfer; tungsten complexes; hydride complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Feb 2023 07:02 |
| Last Modified: | 24 Feb 2023 07:02 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49761 |
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