Kunkely, Horst and Vogler, Arnd (1998) Photo-oxidation of bis[1,2-bis(diphenylphosphino)ferrocene]-palladium(0) in CCl4 induced by ferrocene to solvent charge transfer excitation. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 559 (1-2). pp. 215-217. ISSN 0022-328X, 1872-8561
Full text not available from this repository.Abstract
The electronic spectrum of Pd-0[(PPh2C5H4)(2)Fe-II](2) in CCl4 shows an absorption at lambda(max) = 338 nm that is assigned to a charge transfer-to-solvent (C-TTS) transition from the ferrocene moiety to CCl4. The CTTS excitation leads to the formation of Pd-II[(PPh2C5H4)(2)Fe-II]Cl-2. It is suggested that the irradiation induces initially the generation of Fe-III, which then oxidizes Pd-0 by intramolecular electron transfer. Product formation takes place by a disproportionation of Pd-I. (C) 1998 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; PALLADIUM; PLATINUM; charge transfer; palladium complexes; ferrocene complexes; photochemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Feb 2023 07:37 |
| Last Modified: | 24 Feb 2023 07:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49801 |
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