Brunner, Henri and Winter, Andreas and Nuber, Bernhard (1998) Optically active transition metal compounds 114 - The complexes (eta(3)-C27H33N3)CuCl2 and (eta(3)-C27H33N3)M(CO)(3) (M = Cr, Mo, W) containing the ligand C27H33N3 = N,N ',N ''-tris[((S)-1 '-phenylethyl]hexahydro-1,3,5-triazine. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 558 (1-2). pp. 213-218. ISSN 0022-328X, 1872-8561
Full text not available from this repository.Abstract
The reaction of N,N',N "-tris[(S)-1'-phenylethyl]hexahydro-1,3,5-triazine (2) with anhydrous CuCl2, (CH3CN)(3)Cr(CO)(3), (eta(6)-C7H8)Mo(CO)(3) and (eta(6)-C7H8)W(CO)(3) leads to new chiral complexes, of which (eta(3)-C27H33N3)CuCl2 (3) and eta(3)-(C27H33N3)CrH(CO)(3) (4) are characterized by X-ray structure analyses. In complex 3 the three nitrogen atoms coordinate in two different ways. Complex 4 crystallizes in a layer-structure and contains chiral cavities. (C) 1998 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | hexahydrotriazine ligands; copper; chromium; molybdenum; tungsten; X-ray structure analysis; chirality |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Feb 2023 07:54 |
| Last Modified: | 24 Feb 2023 07:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49809 |
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