Kunkely, Horst and Vogler, Arnd (1998) Photosubstitution of dichloro(2,2 '-diamino-1,1 '-binaphthyl)platinum(II). JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 114 (3). pp. 193-195. ISSN 1010-6030
Full text not available from this repository.Abstract
The absorption spectrum of Pt(DABN)Cl-2 (DABN = 2,2'-diamino-1,1'-binaphthyl) shows a ligand field (LF) band at lambda(max) = 385 nm and intraligand (IL) bands of DABN at shorter wavelengths (lambda(max) = 364, 330, 316, 288, 266, 241, 224 and 212 nm). The photolysis of Pt(DABN)Cl-2 in CH3CN leads to the release of the DABN ligand. The quantum yield of this photosubstitution is phi similar to 0.036 and independent of the irradiating wavelength. It is suggested that this photoreaction is induced by LF or IL excitation. (C) 1998 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | DNA; COMPLEXES; THERAPY; diaminobinaphthyl; platinum complexes; substitution |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Feb 2023 10:33 |
| Last Modified: | 24 Feb 2023 10:33 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49885 |
Actions (login required)
 |
View Item |
