Kunkely, Horst and Vogler, Arnd (1998) Photochemical generation of nitroprusside induced by MLCT excitation of nitrosobenzenepentacyanoferrate(II). JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 114 (3). pp. 197-199. ISSN 1010-6030
Full text not available from this repository.Abstract
Aqueous [Fe-II(CN)(5)(ONPh)](3-) shows a long-wavelength absorption at lambda(max) = 528 nm (epsilon=5300) which is assigned to a MLCT transition terminating at the nitrosobenzene ligand. The photolysis initiated by MLCT excitation proceeds according to the equation [Fe(CN)(5)(ONPh)](3-) + H2O --> [Fe(CN)(5)NO](2-) + C6H6 + OH-. Nitroprusside formed with phi = 0.03 at lambda(irr) = 546 nm. (C) 1998 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | UV ABSORPTION-SPECTRUM; NITRIC-OXIDE; SOLID ARGON; COMPLEXES; NITROSOBENZENE; charge transfer; iron complexes; nitrosobenzene; nitrosyl complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Feb 2023 10:38 |
| Last Modified: | 24 Feb 2023 10:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/49886 |
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