Kunkely, Horst and Vogler, Arnd (1998) Charge transfer interaction in (riboflavin)tricarbonylrhenium(I) chloride. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 53 (4). pp. 423-425. ISSN 0932-0776, 1865-7117
Full text not available from this repository.Abstract
[Re(riboflavin)(CO)(3)Cl] shows intraligand (lambda(max) = 476 and 518 nm) and Re(I) to pi* (riboflavin) metal-to-ligand charge transfer, MLCT, (lambda(max) = 556 nm, in CH3CN) absorptions in close proximity. The MLCT band undergoes a moderate solvent-dependent shift (negative solvatochromism) indicating a partial charge separation in the excited state. The complex is not photoluminescent.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; ELECTROCHEMISTRY; ACID; charge transfer; rhenium complexes; riboflavin |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2023 05:54 |
| Last Modified: | 28 Feb 2023 05:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50007 |
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