Enantioselective catalysis - 120 - New optically active pyrrole-oxazolines

Brunner, Henri and Haßler, Bernd (1998) Enantioselective catalysis - 120 - New optically active pyrrole-oxazolines. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 53 (4). pp. 476-480. ISSN 0932-0776, 1865-7117

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Abstract

14 new optically active pyrrole-oxazolines were synthesised from 2-pyrrole-carbonitrile or methyl 2-pyrrole-carboximidate and chiral amino alcohols. Their use in copper-catalysed enantioselective cyclopropanation reactions gave only low optical yields (3-14%ee).

Item Type: Article
Uncontrolled Keywords: ASYMMETRIC CATALYSIS; CYCLOPROPANATION; OLEFINS; LIGANDS; HYDROSILYLATION; COMPLEXES; KETONES; pyrrole-oxazolines; enantioselectivity; catalysis; cyclopropanations
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner
Depositing User: Dr. Gernot Deinzer
Date Deposited: 28 Feb 2023 05:57
Last Modified: 28 Feb 2023 05:57
URI: https://pred.uni-regensburg.de/id/eprint/50008

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