Slenczka, Alkwin (1998) Electric linear dichroism with a simple interpretation in terms of molecular pendular states. PHYSICAL REVIEW LETTERS, 80 (12). pp. 2566-2569. ISSN 0031-9007, 1079-7114
Full text not available from this repository.Abstract
An anisotropic orientation of the figure axis of electrically dipolar ICI is forced by a strong homogeneous electric field. The molecule is transferred into a pendular state and shows optical anisotropy due to the body fixed molecular transition dipole moment, This holds in exactly the same way for magnetically dipolar molecules in a homogeneous magnetic field. A simple geometric model is applied which simulates all spectral features quantitatively without any fitting procedure for both the electric and the magnetic case. The sparse structure of polarization spectra of such a sample allows for easy reading of spectroscopic constants and study of electronic states of even large molecules.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | POLARIZATION SPECTROSCOPY; AMORPHOUS SOLIDS; SPECTRAL HOLES; NARROWING SPECTROSCOPY; MAGNETIC-FIELDS; LASER FIELDS; ALIGNMENT; ICI |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Alkwin Slenczka |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2023 06:29 |
| Last Modified: | 28 Feb 2023 06:29 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50013 |
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