Brunner, Henri and Störiko, Reinhard and Nuber, Bernhard (1998) Enantioselective catalysis. Part 119: New chiral 2-(2-pyridinyl)oxazoline ligands containing an additional optically active substituent in the pyridine system. TETRAHEDRON-ASYMMETRY, 9 (3). pp. 407-422. ISSN 0957-4166
Full text not available from this repository. (Request a copy)Abstract
The synthesis of novel chiral nitrogen ligands and their precursors is described. They consist of an optically active oxazoline bound to pyridine in the 2-position. In addition, another optically active substituent is attached to the pyridine ring. The effect of the two independent stereogenic units in one ligand was studied in the Rh(I)-catalysed enantioselective hydrosilylation of acetophenone with diphenylsilane. (C) 1998 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC HYDROSILYLATION; KETONES; OLEFINS; ACETOPHENONE; COMPLEXES |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2023 09:09 |
| Last Modified: | 28 Feb 2023 09:09 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50086 |
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