Leirer, Markus and Knör, Günther and Vogler, Arnd (1998) Optical metal-to-ligand charge transfer in ethyl-xanthato(tetracarbonyl) rhenium(I). INORGANIC CHEMISTRY COMMUNICATIONS, 1 (2). pp. 49-50. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
The xanthate complex Re-I(CO)(4)S2COEt was prepared and characterized by elemental analysis and various spectroscopic methods. The electronic spectrum of this compound shows two long-wavelength absorptions which are assigned to intraligand pi pi* (lambda(max) = 278 nm) and Re(I) --> S2COEt- MLCT (lambda(max) = 327 nm) transitions. The MLCT state is not luminescent but reactive. (C) 1998 Elsevier Science S.A.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CARBON-DIOXIDE; optical charge transfer; rhenium complexes; xanthato complexes; carbonyl complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2023 09:43 |
| Last Modified: | 28 Feb 2023 09:43 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50105 |
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