Kunkely, Horst and Vogler, Arnd (1998) Photoreactivity of titanocene pentasulfide. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 53 (2). pp. 224-226. ISSN 0932-0776, 1865-7117
Full text not available from this repository.Abstract
The electronic spectrum of Cp2TiS5 shows a long-wavelength absorption at lambda(max) = 492 nm which is assigned to the lowest-energy S-5(2-)-->Ti-IV ligand-to-metal charge transfer(LMCT) transition. The photolysis of the complex in CH2Cl2 leads to the formation of Cp2TiCl2 and elemental sulfur. II is suggested that LMCT excitation initiates a reductive elimination with the extrusion of S-5 while the reduced titanocene is reoxidized by the solvent.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; charge transfer; titanium complexes; sulfide complexes; photochemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2023 10:31 |
| Last Modified: | 28 Feb 2023 10:31 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50145 |
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