Kunkely, Horst and Leirer, Markus and Vogler, Arnd (1998) Photoreactivity of Fremy's salt in aqueous solution. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 112 (1). pp. 9-11. ISSN 1010-6030
Full text not available from this repository.Abstract
The absorption spectrum of Fremy's salt, K-2[ON(SO3)(2)], in water shows two bands at lambda(max) = 545 and 248 nm which are assigned to sigma(b) --> pi(n) and pi(n) --> sigma* transitions, respectively. The photolysis of Fremy's salt leads to a decomposition. It is assumed that a homolytic cleavage of a N-S bond is the primary photochemical step. (C) 1998 Elsevier Science S.A.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ULTRAVIOLET-ABSORPTION SPECTRUM; ELECTRONIC-SPECTRA; GEOMETRIES; CONSTANTS; HGX3; Fremy's salt; absorption spectra |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2023 10:38 |
| Last Modified: | 28 Feb 2023 10:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50152 |
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