Kunkely, Horst and Vogler, Arnd (1998) Photoredox reaction of (p-dimethylaminopyridine)osmium(VIII)tetroxide induced by ligand-to-metal charge transfer excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 1 (1). pp. 7-9. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
The complex OsO4(4-dimethylaminopyridine) shows a long-wavelength adsorption at lambda(max)=473 nm which is assigned to a ligand-to-metal charge transfer (LMCT) transition from the pyridine ligand to Os(VIII). LMCT excitation of the complex dissolved in ethanol leads to a reduction of Os(VIII) to Os(VI) and oxidation of ethanol to acetaldehyde with phi=0.1 at lambda(irr)=436 nm.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN-GROUP ELEMENTS; TRANSITION-METALS; MULTIPLE BONDS; ORGANORHENIUM(VII) OXIDES; ASYMMETRIC DIHYDROXYLATION; BASE ADDUCTS; METHYLTRIOXORHENIUM(VII); PHOTOCHEMISTRY; BEHAVIOR; charge transfer; photochemistry; osmium complexes; pyridine complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Mar 2023 08:34 |
| Last Modified: | 01 Mar 2023 08:34 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50216 |
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