Quintero-Duque, Samuel and Fleischer, Ivana (2017) Tandem and One-Pot Hydroformylation/Michael Reactions of Acrylates. SYNTHESIS-STUTTGART, 49 (4). pp. 925-932. ISSN 0039-7881, 1437-210X
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The combination of various reactions in one operational step leads to many advantages in synthetic strategies, such as a lower consumption of resources, effort, arid time, when intermittent workup and purification steps can be avoided. The hydroformylation reaction of acrylates gives access to 2-formylpropanoates, which thanks to their structural features constitute useful intermediates in the synthesis of more complex compounds. Herein, we report a simple arid convenient one-pot strategy to synthesize functionalized carbonyl, compounds starting from these readily available substrates, via tandem or one-pot hydroformylation, Michael addition, and aldol reactions,
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | RHODIUM-CATALYZED HYDROFORMYLATION; STEREOSELECTIVE HYDROFORMYLATION; ASYMMETRIC HYDROFORMYLATION; SELECTIVE HYDROFORMYLATION; UNSATURATED ESTERS; METHYL ACRYLATE; COMPLEXES; ALKENES; LIGANDS; OLEFINS; hydroformylation; acrylates; rhodium; one port; tandem; Michael addition |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Ivana Fleischer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Dec 2018 13:01 |
| Last Modified: | 26 Feb 2019 07:28 |
| URI: | https://pred.uni-regensburg.de/id/eprint/503 |
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