Krienke, H. and Barthel, J. (1998) MSA models of ion association in electrolyte solutions. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 204. pp. 71-83. ISSN 0942-9352
Full text not available from this repository.Abstract
The subject of the investigation is the role of ion association in electrolyte solutions with and without the inclusion of the dipolar interaction of ion pairs. The corresponding chemical models in the mean spherical approximation (MSA) on MM level, and a physical model which - in the limit of strong electrostatic association - yields a parameter-free theory, are used to calculate thermodynamic excess functions. The model calculations are compared with experimental results.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MEAN SPHERICAL APPROXIMATION; GENERALIZED VIRIAL EXPANSIONS; HARD-SPHERES; PRIMITIVE MODEL; EQUILIBRIUM; CONDUCTANCE; EQUATION; MIXTURE; SYSTEMS; electrolyte theory; ion pairs; chemical models; activity coefficient |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Mar 2023 10:32 |
| Last Modified: | 01 Mar 2023 10:32 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50321 |
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