Polyhalogenated cyclopentadienes in [4+2] cycloadditions: Preparative aspects

Eibler, Ernst and Burgemeister, Thomas and Höcht, Peter and Prantl, Bernhard and Roßmaier, Henry and Schuhbauer, Hans Markus and Wiest, Hubert and Sauer, Jürgen (1997) Polyhalogenated cyclopentadienes in [4+2] cycloadditions: Preparative aspects. LIEBIGS ANNALEN-RECUEIL, 1997 (12). pp. 2451-2469. ISSN 0947-3440

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Abstract

[4+2] Cycloadditions of cyclopentadienes 1a-1i with aryl-substituted cyclic and open-chain dienophiles usually gave single endo-cycloadducts in high yield. Assignment of the product structures involved H-1-NMR spectroscopy including (H-1,H-1) long-range coupling and (H-1,F-19) through-bond and through-space coupling.

Item Type: Article
Uncontrolled Keywords: DIELS-ALDER REACTIONS; CRYSTAL-STRUCTURE; cycloadditions; structure elucidation; through-space interactions; cyclopentadienes; 1,2,4-triazoline-3,5-diones
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 01 Mar 2023 12:10
Last Modified: 01 Mar 2023 12:10
URI: https://pred.uni-regensburg.de/id/eprint/50372

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