Brunner, Henri and Leis, Franz and Wachter, Joachim and Nuber, Bernhard (1997) Influence of coordinated Cr(CO)(5) groups on the fragmentation of realgar: Synthesis and characterization of the novel mixed Zintl ion complex (C5Me4Et)Co(eta(4)-As6S). ORGANOMETALLICS, 16 (23). pp. 4954-4955. ISSN 0276-7333, 1520-6041
Full text not available from this repository.Abstract
A complex containing the novel mixed Zintl ion As6S2- is obtained from the reaction of (Cp2Co2)-Co-x(CO)(2) (Cp-x = C5Me4Et) with As4S4[Cr(CO)(5)](n) (n = 1, 2) in boiling xylene. (CpCoAs6S)-Co-x (1) is formed along with already known (Cp2CO2As6)-C-x (2), (CpCo)-Co-x(CO)As4S3 (3), and (Cp2Co2As2S3)-Co-x (4). The product distribution and nature of the products show that the Cr(CO)(5) groups play the role of sulfur-abstracting reagents rather than that of protective groups.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CYCLO-P4 LIGAND; INSERTION; P-4 |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Mar 2023 08:54 |
| Last Modified: | 02 Mar 2023 08:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50414 |
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