Barthel, Josef and Neueder, R. and Schröder, A. (1997) Temperature dependence of activity coefficients and Gibbs energies of transfer of LiBr in acetonitrile, dimethyl sulfoxide, and N,N-dimethylacetamide from EMF measurements. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 75 (11). pp. 1500-1507. ISSN 0008-4042
Full text not available from this repository.Abstract
Electromotive force (EMF) measurements based on the redox reaction LixHg(1) + TlBr(s) reversible arrow LiBr(solv, C-LiBr) + TlxHg(1) are reported for solutions of LiBr at concentrations 0.005 < c(LiBr)/(mol dm(-3)) < 0.1 in acetonitrile (AN), dimethyl sulfoxide (DMSO), and N,N-dimethylacetamide (DMA) in the temperature range 278.15 < T/K < 308.15. Gibbs energies of transfer and activity coefficients are estimated. The association constants of LiBr in AN, DMSO, and DMA from EMF measurements and the enthalpy of transfer AN --> DMSO are compared to those from other methods of determination.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTROLYTES; temperature-dependent EMF measurements; aprotic solvents; LiBr; TlBr(s)vertical bar TlxHg(1) electrode; activity coefficients; transfer quantities |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Mar 2023 09:20 |
| Last Modified: | 02 Mar 2023 09:20 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50422 |
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