Oldenburg, Karin and Vogler, Arnd (1997) Optical metal-to-metal charge transfer in [Fe-III(C5H4PPh2)(2)Re-I(CO)(3)Cl](+). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 544 (1). pp. 101-103. ISSN 0022-328X, 1872-8561
Full text not available from this repository.Abstract
The electronic spectrum of the binuclear complex ion [Fe-III(C5H4PPh2)(2)Re-1(CO)(3)Cl](+) in CH2Cl2 shows a long-wavelength absorption at lambda(max) = 700 nm (epsilon = 206 M-1 cm(-1)) which is assigned to a Re-I --> Fe-III MMCT transition. An analysis according to the Hush model confirms the assumption that the complex contains weakly coupled metal centers and is thus a type II compound (Robin and Day classification). (C) 1997 Elsevier Science S.A.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MIXED-VALENCE COMPLEXES; CARBONYL; RHENIUM; LIGAND; ferrocenium; rhenium carbonyl complex; charge transfer |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Mar 2023 06:41 |
| Last Modified: | 28 Mar 2023 06:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50483 |
Actions (login required)
 |
View Item |
