A time domain reflectometer for dielectric relaxation spectroscopy of electrolyte solutions

Buchner, Richard and Barthel, J. (1997) A time domain reflectometer for dielectric relaxation spectroscopy of electrolyte solutions. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 101 (10). pp. 1509-1516. ISSN 0005-9021

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Abstract

A time domain reflectometer for dielectric relaxation spectroscopy of electrolyte solutions in the temperature range of -45 less than or equal to theta/degrees C less than or equal to 90 is presented. With a set of cutoff cells differing in their cell constants, pure solvents covering the permittivity range of 7 less than or equal to epsilon less than or equal to 228 and their concentrated electrolyte solutions (kappa>1 Omega(-1) m(-1)) can be investigated at frequencies of 0.05 less than or equal to v/GHz less than or equal to 9. In combination with the transmission line system of our laboratory (8.5 less than or equal to v/GHz less than or equal to 89) dielectric dispersion, epsilon'(v), and total loss, eta ''(v) = epsilon ''(v)+kappa/(2 pi v epsilon(0)) can be determined with 2% accuracy relative to epsilon.

Item Type: Article
Uncontrolled Keywords: COMPLEX PERMITTIVITY; LIQUIDS; RANGE; dielectrics; liquids; methods and systems; solutions
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Depositing User: Dr. Gernot Deinzer
Date Deposited: 28 Mar 2023 06:46
Last Modified: 28 Mar 2023 06:46
URI: https://pred.uni-regensburg.de/id/eprint/50496

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