Brunner, Henri and Reimer, Alfred (1997) New chiral expanded phosphanes derived from substituted deltacyclenes. CHEMISCHE BERICHTE-RECUEIL, 130 (10). pp. 1495-1498. ISSN 0009-2940
Full text not available from this repository.Abstract
The suitability of enantiomerically pure deltacyclenes as building blocks in the synthesis of expanded phosphanes was examined. Different substituted deltacyclenes were irradiated with diphenylphosphane and three bisphosphanyl derivatives. With these P-H addition reactions, new chiral deltacyclane-derived phosphorus ligands were synthesized. They were tested in the Rh-catalyzed asymmetric hydrogenation of (Z)-(alpha)-N-acetamidocinnamic acid and in the Pd-catalyzed asymmetric allylation of 1,5-dimethylbarbituric acid.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; PHOSPHINES; PHOSPHORUS; LIGANDS; ACID; deltacyclenes; deltacyclanes; P-H addition reactions; chiral phosphanes; enantioselective catalysis |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Mar 2023 07:00 |
| Last Modified: | 28 Mar 2023 07:00 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50500 |
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