Kunkely, Horst and Vogler, Arnd (1997) Photochemistry of chlorocarbonyl gold(I). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 541 (1-2). pp. 177-179. ISSN 0022-328X, 1872-8561
Full text not available from this repository.Abstract
The complex Au(CO)Cl shows a long wavelength absorption at lambda(max) = 250 nm which is assigned to a metal-centered ds transition. In the solid state this excited ds state is emissive (lambda(max) = 663 nm) while in solution it is reactive. It is suggested that CO is released in the primary photochemical step. In CH2Cl2 the photolysis of Au(CO)Cl leads finally to a disproportionation with the formation of AuCl3 and metallic gold. (C) 1997 Elsevier Science S.A.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | RAY CRYSTAL-STRUCTURE; SPECTROSCOPIC PROPERTIES; PHOTOPHYSICAL PROPERTIES; 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE TPA; PHOSPHINE COMPLEXES; LUMINESCENCE; EMISSION; STATE; SPECTRA; PHOTOLUMINESCENCE; gold complexes; absorption spectra; photoluminescence; photochemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 30 Mar 2023 09:49 |
| Last Modified: | 30 Mar 2023 09:49 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50650 |
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