Arene-arene stacking in cis-bis[2-(2-thienyl-C-3)pyridine-N]platinum(II)

Breu, Josef and Range, Klaus-Jürgen and von Zelewsky, Alex and Yersin, Hartmut (1997) Arene-arene stacking in cis-bis[2-(2-thienyl-C-3)pyridine-N]platinum(II). ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 53. pp. 562-565. ISSN 0108-2701, 1600-5759

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Abstract

In the crystal structure of the title complex, [Pt(C9H6NS)(2)], although the aromatic ligands are coordinated to a central heavy metal stem. T-shaped and shifted pi-stacked arrangements of the aromatic moieties are preferred, leading to a sandwich herring-bone type of crystal-packing motif. The crystal structure is therefore consistent with the view that the arene-arene interactions are determined by electrostatics (multipole-multipole).

Item Type: Article
Uncontrolled Keywords: CRYSTAL-STRUCTURES; CHARGE-TRANSFER; COMPLEXES; PLATINUM
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Klaus-Jürgen Range
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Depositing User: Dr. Gernot Deinzer
Date Deposited: 27 Apr 2023 09:08
Last Modified: 27 Apr 2023 09:08
URI: https://pred.uni-regensburg.de/id/eprint/50816

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