Brunner, Henri and Reimer, A. (1997) Enantioselective catalysis .112. New chiral tertiary alcohols on the basis of deltacyclanes as precursors for hydroperoxides. BULLETIN DES SOCIETES CHIMIQUES BELGES, 106 (5). pp. 267-272. ISSN 0037-9646
Full text not available from this repository.Abstract
Norbornadiene was reacted with 2-methyl-3-butin-2-ol 1 in an enantioselective homo Diels-Alder reaction to yield the deltacyclene 2 with 92% ee. 2 was hydrogenated stereoselectively to give the enantiomerically pure, deltacyclane-based tertiary alcohol 3, a candidate for conversion into an optically active hydroperoxide for enantioselective oxidation reactions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | DIELS-ALDER REACTION; ASYMMETRIC EPOXIDATION; SYSTEM |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 May 2023 06:42 |
| Last Modified: | 09 May 2023 06:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50839 |
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