Breu, Josef and Butz, Thomas and Range, Klaus-Jürgen and Sauer, Jürgen (1997) Configurations of cycloadducts formed in asymmetric intramolecular Diels-Alder reactions. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 53 (4). pp. 515-517. ISSN 0108-2701, 1600-5759
Full text not available from this repository.Abstract
Intramolecular cycloaddition reactions of two furfuryl fumarates yield, after crystallization, pure diastereomers of oxabicyclo[2.2.1]heptene derivatives which are versatile starting points for the total synthesis of natural products. The crystal structures of the adducts, menthyl (3aS,6R,7R,7aR)-1,3,3a,6,7,7a-hexahydro-3,3-dimethyl-1-oxo-3a,6- epoxyisobenzofuran-7-carboxylate, C21H30O5, and methyl syn-3-tert-butyl-1,3,3a,6,7,7a-hexahydro-1- oxo-3a,6-epoxyisobenzofuran-7-carboxylat, C14H18O5, establish the configuration at the chiral centers and provide insights into the factors controlling the diastereomeric differentiation.
| Item Type: | Article |
|---|---|
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Klaus-Jürgen Range Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 May 2023 07:51 |
| Last Modified: | 09 May 2023 07:51 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50876 |
Actions (login required)
 |
View Item |
