Kunkely, Horst and Vogler, Arnd (1997) Intramolecular oxidative addition of diperoxotriaminechromium(IV) induced by d sigma* metal-to-ligand charge transfer excitation. INORGANICA CHIMICA ACTA, 256 (2). pp. 169-170. ISSN 0020-1693, 1873-3255
Full text not available from this repository.Abstract
The complex Cr(IV)(O-2)(2)(NH3)(3) shows an absorption band at lambda(max) = 390 nm which is assigned to a d sigma* metal-to-ligand charge transfer (MLCT) transition from Cr(IV) to the coordinated peroxide. Upon MLCT excitation the aqueous complex undergoes an intramolecular oxidative addition of peroxide to Cr(IV) leading to chromate with phi = 0.35 at lambda(irr) = 254 nm.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; photochemistry; charge transfer; chromium complexes; ammine complexes; peroxo complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 11 May 2023 09:40 |
| Last Modified: | 11 May 2023 09:40 |
| URI: | https://pred.uni-regensburg.de/id/eprint/50966 |
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