Kunkely, Horst and Vogler, Arnd (1997) Photoreactivity of hematoporphyrin IX-dichloroplatinum(II). Light-induced release and activation of free base hematoporphyrin. INORGANICA CHIMICA ACTA, 254 (2). pp. 417-419. ISSN 0020-1693, 1873-3255
Full text not available from this repository.Abstract
The complex Pt(II) (hematoporphyrinH(2))Cl-2 which contains free base porphyrin as a bidentate ligand is light sensitive. In DMF a photosubstitution takes place. The porphyrin is released with phi similar to 2 X 10(-3) at lambda(irr) = 405 nm. It is assumed that the photolysis originates from a ligand field state which is populated from pi pi* intraligand states. In a secondary photolysis the porphyrin undergoes a decomposition in agreement with previous results.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTODYNAMIC THERAPY; PORPHYRINS; COMPLEXES; photochemistry; porphyrin complexes; platinum(II) complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 May 2023 08:00 |
| Last Modified: | 17 May 2023 08:00 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51099 |
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