The first helical-chiral phosphane ligands: rac-[5]- and rac-[6]-Heliphos

Terfort, Andreas and Görls, Helmar and Brunner, Henri (1997) The first helical-chiral phosphane ligands: rac-[5]- and rac-[6]-Heliphos. SYNTHESIS-STUTTGART, 1997 (1). pp. 79-86. ISSN 0039-7881, 1437-210X

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Abstract

The syntheses of two helical, chiral phosphanes in their racemic forms are described. Their helicene backbone was built up using an improved photocyclization approach. The phosphorus functionalities were introduced in the last step. Up to now, separation of the enantiomers of the helicene phosphanes could be achieved analytically but not on a preparative scale.

Item Type: Article
Uncontrolled Keywords: RECOGNITION; helical phosphanes; enantiomeric separation; racemic mixture
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner
Depositing User: Dr. Gernot Deinzer
Date Deposited: 25 May 2023 09:39
Last Modified: 25 May 2023 09:39
URI: https://pred.uni-regensburg.de/id/eprint/51255

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