Barthel, J. and Buestrich, R. and Carl, E. and Gores, H. J. (1996) A new class of electrochemically and thermally stable lithium salts for lithium battery electrolytes .3. Synthesis and properties of some lithium organoborates. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 143 (11). pp. 3572-3575. ISSN 0013-4651, 1945-7111
Full text not available from this repository.Abstract
Synthesis, analysis, and purification of new lithium salts for lithium batteries, lithium bis[tetrafluoro-1,2-benzenediolato(2-)-O,O']borate and Lithium bis[2,3-naphthalenediolato(2-)-O,O']borate described, and the results of electrochemical studies of these salts and of lithium bis[3-fluoro-1,2-benzenediolato(2-)-O,O']borate in propylene carbonate are reported. The effect of the electron-withdrawing substituent fluorine results in an increase of the electrochemical window by 0.1 V/fluorine per one chelate Ligand. The slope, which can be calculated from the linear correlation of the highest occupied molecular orbital energies with anodic oxidation potentials is -3.0 eV/V, a value equal to that known for aryl berates and fluoroaryl berates.
| Item Type: | Article |
|---|---|
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Heiner Jakob Gores |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Jun 2023 09:40 |
| Last Modified: | 21 Jun 2023 09:40 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51386 |
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