Brunner, Henri and Bügler, Jürgen and Nuber, Bernhard (1996) Optically active transition metal complexes .111. Synthesis and structure of a new thioamidato rhodium(I) complex. TETRAHEDRON-ASYMMETRY, 7 (11). pp. 3095-3098. ISSN 0957-4166
Full text not available from this repository.Abstract
The reaction of [Rh(cod)Cl](2) with deprotonated N-[(A)-1-phenylethyl]thiobenzamide affords the new complex 1. In the solid state 1 exists as a binuclear complex with the two sulfur atoms of two thioamidato ligands bridging the Rh atoms. The molecular structure of 1 was determined by X-ray analysis: C46H52N2S2Rh2, monoclinic, space group C2, a - 10.564(4), b = 16.864(5), c = 23.548(7), beta = 95.05(3)degrees, Z = 2 x 2, R = 0.046, R(w) = 0,039. Complex 1 equilibrates with an isomer in solution at room temperature. Copyright (C) 1996 Published by Elsevier Science Ltd
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ENANTIOSELECTIVE HYDROSILYLATION; THIAZOLIDINE CATALYSTS; LIGANDS |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Jun 2023 10:10 |
| Last Modified: | 21 Jun 2023 10:10 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51404 |
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