Brunner, Henri and Nuber, Bernhard and Prommesberger, Markus (1996) Optically active transition metal complexes .110. New rhodium(I) complexes with 2-pyridinecarboxamido ligands. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 523 (2). pp. 179-185. ISSN 0022-328X, 1872-8561
Full text not available from this repository.Abstract
The reaction of [Rh(cod)Cl](2) with the 2-pyridinecarboxamides 1a-e in the presence of base affords the new complexes 2a-e in which the amides act as bidentate ligands coordinating via pyridine-N and the deprotonated amide-N. The structure of 2a was established by X-ray structure analysis: C14H17N2ORh, triclinic, space group P (1) over bar (No. 2), a = 10.034(4) Angstrom, b = 10.146(6) Angstrom, c = 13.165(4) Angstrom, alpha = 108.09(3)degrees, beta = 91.93(3)degrees, gamma= 89.90(4)degrees Z = 2 x 2, R = 0.039, R(w) = 0.036.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | X-RAY STRUCTURE; CRYSTAL-STRUCTURE; CATALYST; rhodium; amide; optically active transition metal complexes; 2-pyridinecarboxamide ligands; X-ray structure analysis; (S)-1-phenylethyl substitution |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Jun 2023 08:52 |
| Last Modified: | 22 Jun 2023 08:52 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51413 |
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