Barthel, Josef and Gores, Heiner J. and Lohr, C. M. and Seidl, J. J. (1996) Taylor dispersion measurements at low electrolyte concentrations .1. Tetraalkylammonium perchlorate aqueous solutions. JOURNAL OF SOLUTION CHEMISTRY, 25 (10). pp. 921-935. ISSN 0095-9782, 1572-8927
Full text not available from this repository.Abstract
An equipment for the determination of mutual diffusion coefficients using the Taylor's dispersion technique is described. The radius of the capillary was determined with the help of various calibration methods. Diffusion coefficients of aqueous tetraalkylammonium perchlorates, Me(4)NClO(4), and E(4)NClO(4), were measured at 25 degrees C in the concentration range 10(-3) to 5x10(-2) mol-dm(-3), and the slightly soluble Pr4NClO4 up to 1x10(-2) mol-dm(-3). The slope of linear plots of D vs. root c is in agreement with theory, in contrast to the limiting values D-0, which all deviate by about -5% from the Nernst-Hartley values.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MUTUAL-DIFFUSION-COEFFICIENTS; TEMPERATURE-DEPENDENCE; WATER; 25-DEGREES-C; MIXTURES; ETHANOL; ISOMERS; HEXANE; Taylor dispersion technique; mutual diffusion coefficient; aqueous tetraalkylammonium perchlorate solutions |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Jun 2023 09:45 |
| Last Modified: | 22 Jun 2023 09:45 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51444 |
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