Kunkely, Horst and Vogler, Arnd (1996) Photoreactivity of buckminsterfullerene-bis(triphenylphosphite)platinum(0) induced by metal-to-ligand charge transfer excitation. INORGANICA CHIMICA ACTA, 250 (1-2). pp. 375-377. ISSN 0020-1693, 1873-3255
Full text not available from this repository.Abstract
The complex C60Pt[P(OPh)(3)](2) displays C-60 pi pi* intraligand bands in the UV-Vis region and a long-wavelength absorption at lambda(max) = 770 nm which is assigned to a metal-to-ligand charge transfer (MLCT) transition from platinum to fullerene. The irradiation of the complex leads to the population of the reactive MLCT state and subsequently to the dissociation (C60Pt[P(OPh)(3)](2) --> C-60 + Pt[P(OPh)(3)](2)) in the primary photochemical step. Product formation takes place by the interception of Pt[P(OPh)(3)](2) with suitable scavengers such as CHCl3 or O-2.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOPHYSICAL PROPERTIES; ELECTRONIC-STRUCTURE; TRIPLET C-60; FLUORESCENCE; C-70; C60; FULLERENES; BUCKMINSTERFULLERENE; COMPLEXES; EMISSION; charge transfer; platinum(0) complexes; fullerene complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Jun 2023 05:45 |
| Last Modified: | 29 Jun 2023 05:45 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51505 |
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