Brunner, Henri and Net, Gemma (1996) Enantioselective catalysis .101. Synthesis and coordination properties of (3'S,4'S)-(+)-1,2-Bis(3',4'-dimethoxyphospholano)benzene, a new chiral diphosphane. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 51 (8). pp. 1210-1212. ISSN 0932-0776, 1865-7117
Full text not available from this repository.Abstract
A new bisphospholane, BDPB, derived from 1,2-bisphosphanobenzene and tartaric acid as well as the complex [Rh(COD)(BDPB)]PF6 were synthesized. The strong binding of BDPB to metals and the presence of four functional groups in the periphery of the molecule make this bisphospholane a good starting point for new expanded bisphosphanes.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC ALLYLIC ALKYLATION; TARTARIC ACID; PHOSPHINES; LIGANDS; chiral bisphosphanes; expanded phosphanes; rhodium complexes; cyclic sulfates |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 04 Jul 2023 07:46 |
| Last Modified: | 04 Jul 2023 07:46 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51592 |
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