Knör, Günther and Vogler, Arnd and Roffia, Sergio and Paolucci, Francesco and Balzani, Vincenzo (1996) Switchable photoreduction pathways of antimony(v) tetraphenylporphyrin. A potential multielectron transfer photosensitizer. CHEMICAL COMMUNICATIONS, 1996 (14). pp. 1643-1644. ISSN 1359-7345, 1364-548X
Full text not available from this repository.Abstract
Photoreduction of [Sb-V(tpp)(OH)(2)](+) (tpp = dianion of 5,10,15,20-tetraphenylporphyrin) yields either the metastable pi-radical anion [Sb-V(tpp(.-))(OH)(2)] or the two-electron reduced [Sb-III(tpp)](+) complex; product formation can be channelled in the desired direction by an appropriate choice of the reaction medium and dioxygen regenerates the starting compound.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PI-RADICAL ANIONS; ONE-ELECTRON; REDUCTION; PORPHYRINS; WATER |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Jul 2023 04:37 |
| Last Modified: | 05 Jul 2023 04:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51594 |
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