Oldenburg, Karin and Vogler, Arnd and Miko, Ildikó and Horvath, Ottó (1996) Photoredox decomposition of tin(II), lead(II), antimony(III) and bismuth(III) iodide complexes in solution. INORGANICA CHIMICA ACTA, 248 (1). pp. 107-110. ISSN 0020-1693, 1873-3255
Full text not available from this repository.Abstract
The main group metal complexes SnI3-, PbI3-, SbI4- and BiI4- display long-wavelength absorption bands which are assigned to sp/LMCT transitions. The photochemistry of these complexes is determined by the CT character of their lowest-energy excited state. The photolysis in acetonitrile leads to a photoredox decomposition which yields I-3(-) and the elemental metals as final products. The results of the continuous photolysis are supplemented by observations on the flash photolysis of PbI3-.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN GROUP-METALS; COORDINATION-COMPOUNDS; PHOTOCHEMISTRY; photochemistry; electronic spectra; main group metal complexes; iodide complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Jul 2023 05:27 |
| Last Modified: | 05 Jul 2023 05:27 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51615 |
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