Swelling of subchains of a single polymer chain with excluded volume in two and three dimensions: A Monte Carlo study

Wittkop, Markus and Kreitmeier, Stefan and Göritz, Dietmar (1996) Swelling of subchains of a single polymer chain with excluded volume in two and three dimensions: A Monte Carlo study. MACROMOLECULES, 29 (13). pp. 4754-4758. ISSN 0024-9297, 1520-5835

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Abstract

The expansion of subchains of a single excluded volume chain in two and three dimensions was studied using the bond-fluctuation model. The average expansion factor of subchains containing n segments shows a maximum for n < N, where N is the number of bonds of the whole chain. The subchains are more swollen than an isolated chain containing the same number of segments, and this excess swelling is most pronounced in the center of the chain. Both the behavior of the average expansion factor and the excess swelling can be described using the analytical results of Duplantier and of Schafer and Baumgartner, particularly in three dimensions.

Item Type: Article
Uncontrolled Keywords: BOND FLUCTUATION METHOD; DYNAMIC PROPERTIES; LINEAR-POLYMERS; CROSSOVER; STATISTICS; SIMULATION; EXPANSION; ALGORITHM; THETA; MELTS
Subjects: 500 Science > 530 Physics
Divisions: Physics > Institute of Experimental and Applied Physics > Alumni or Retired Professors > Group Dietmar Göritz
Depositing User: Dr. Gernot Deinzer
Date Deposited: 05 Jul 2023 06:36
Last Modified: 05 Jul 2023 06:36
URI: https://pred.uni-regensburg.de/id/eprint/51641

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