Kaiser, A. and Wiegrebe, Wolfgang (1996) 1,3-diphenylpropan-1,3-diamines .9. Reaction of alpha-chlorooxime ethers with alpha-lithiobenzylamines. MONATSHEFTE FUR CHEMIE, 127 (6-7). pp. 763-774. ISSN 0026-9247, 1434-4475
Full text not available from this repository.Abstract
The carbanions of the benzylamine derivatives 1-4 have been reacted with alpha-chlorooxime ether 5 in order to gel precursors of 1,3-diphenylpropane-1,3-diamines. Isonitrile 1 afforded the expected result, whereas lithiated benzamide 2 underwent oxidative dimerization and transmetallated chlorooxime derivative 5. Isoxazolidine 3 gave the condensation product 21 as a mixture of diastereomers; treatment of imine 4 led to the desired amine-oxime 15 in low yield.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 1,3-diphenylpropane-1,3-diamines; benzylamine carbanions; alpha-chloroacetophenoneoxime O-methyl ether |
| Subjects: | 600 Technology > 615 Pharmacy |
| Divisions: | Chemistry and Pharmacy > Institute of Pharmacy > Alumni or Retired Professors > Prof. Wiegrebe |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 06 Jul 2023 05:26 |
| Last Modified: | 06 Jul 2023 05:26 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51685 |
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