Breu, Josef and Stoll, A. J. (1996) Tris(1,10-phenanthroline)ruthenium(II) bis(hexafluorophosphate). ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 52. pp. 1174-1177. ISSN 0108-2701, 1600-5759
Full text not available from this repository.Abstract
[Ru(phen)(3)](PF6)(2) (phen = 1, 10-phenanthroline), [Ru(C12H8N2)(3)](PF6)(2), is homostructural with the perchlorate monohydrates of the Cu-II, Co-II, Os-II and Fe-II analogues. This homomorphism is notable in view of the widely differing metal-atom environments and counterion sizes, and suggests that the packing arrangement is a general and accomodating one among tris(1,10-phenanthroline)metal(II) complexes. While [Ru(bpy)(3)](PF6)(2) is built up from homochiral layers, [Ru(phen)(3)](PF6)(2) is composed of rigorously racemic layers of complex cations parallel to the bc plane, with counterions sandwiched between. The average length of the Ru-N bonds [2.063 (4) Angstrom] and the average ligand bite angle [79.8 (2)degrees] compare well with the values published for [Ru(bpy)(3)](PF6)(2) [2.056 (2) Angstrom and 78.7 (1)degrees, respectively].
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURES; MONOHYDRATE |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 06 Jul 2023 06:28 |
| Last Modified: | 06 Jul 2023 06:28 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51704 |
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