Breu, Josef and Belser, Peter and Yersin, Hartmut (1996) Tris(4,4'-bipyrimidine)ruthenium(II) bis(hexafluorophosphate) acetone solvate. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, C52. pp. 858-861. ISSN 0108-2701, 1600-5759
Full text not available from this repository.Abstract
The molecular structure of tris(4,4'-bipyrimidine)ruthenium(II) {[Ru(bpm)(3)](2+)} in the title compound {[Ru(C8H6N4)(3)](PF6)(2).C3H6O} is similar to that of tris(2,2'-bipyridine)ruthenium(II) {[Ru(bpy)(3)](2+)}. However, replacement of C by N in the heterocyclic ring alters the molecular electrostatic potential of the complex cation and hence the chiral recognition and self-assembling, yielding a crystal-packing pattern that is unique among known structures of related trisdiimine-metal complexes.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURES; COMPLEXES |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Nov 2023 06:09 |
| Last Modified: | 02 Nov 2023 06:09 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51776 |
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