Wittkop, Markus and Kreitmeier, Stefan and Göritz, Dietmar (1996) Monte Carlo simulations of the dynamics of single polymer chains above and below the Theta-temperature. COMPUTATIONAL & THEORETICAL POLYMER SCIENCE, 6 (1-2). pp. 41-47. ISSN 1052-0643
Full text not available from this repository.Abstract
The dynamic properties of a single polymer chain in two and three dimensions at different temperatures was studied using the bond-fluctuation model. Above T-Theta they are in agreement with the Rouse model, but below T-Theta differences occur: the center of mass diffusion becomes anomalous, the relaxation times tau(i) rise with the chain length N by a power law of the form tau(i)(N) similar to N-2+3/d (d being the dimension of space) and the diffusion coefficient D-N behaves as D-N similar to N--(2+3/d). The anomalous diffusion of the center of mass can be described by t(b) with b = (2+d)/(3+2d) (t being the time).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TO-COIL TRANSITION; SELF-AVOIDING WALKS; BOND FLUCTUATION METHOD; 2 DIMENSIONS; COLLAPSE TRANSITION; QUANTITATIVE THEORY; RENORMALIZATION-GROUP; COMPUTER-SIMULATION; CONSISTENT APPROACH; GLOBULE TRANSITION; Monte Carlo simulation; single polymer chain; dynamic properties; temperature dependence |
| Subjects: | 500 Science > 530 Physics |
| Divisions: | Physics > Institute of Experimental and Applied Physics > Alumni or Retired Professors > Group Dietmar Göritz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Nov 2023 09:52 |
| Last Modified: | 02 Nov 2023 09:52 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51885 |
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