Lambert, Christoph and Lopez-Solera, Isabel and Raithby, Paul R. (1996) Solid-state and electronic structure of benzoxazol-2-ylidene-triphenylborane complex. ORGANOMETALLICS, 15 (1). pp. 452-455. ISSN 0276-7333, 1520-6041
Full text not available from this repository.Abstract
The X-ray structure of the title compound (synthesized by the reaction of 2-lithiobenzoxazole with triphenylborane and subsequent hydrolysis with water) reveals in comparison with the MP2(FC)/6-31G* optimized structures of the model compound oxazol-2-ylidene-borane complex, the free oxazol-2-ylidene carbene, and the oxazolium cation that the borane complex is a true main-group metal carbene complex of the Fischer type and that if fends to be more similar to the free carbene than to the oxazolium cation.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BORON-STABILIZED N,O-CARBENES; CARBENE; ADDUCT |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Nov 2023 11:00 |
| Last Modified: | 14 Nov 2023 11:00 |
| URI: | https://pred.uni-regensburg.de/id/eprint/51999 |
Actions (login required)
 |
View Item |
